A Scaling Theory of the Collapse Transition in Geometric Cluster Models of Polymers and Vesicles

Much effort has been expended in the past decade to calculate numerically the exponents at the collapse transition point in walk, polygon and animal models. The crossover exponent φ has been of special interest and sometimes is assumed to obey the relation 2− α = 1/φ with the α the canonical (thermodynamic) exponent that characterises the divergence of the specific heat. The reasons for the validity of this relation are not widely known. We present a scaling theory of collapse transitions in such models. The free energy and canonical partition functions have finite–length scaling forms whilst the grand partition function has a tricritical scaling form. The link between the grand and canonical ensembles leads to the above scaling relation. We then comment on the validity of current estimates of the crossover exponent for interacting self avoiding walks in two dimensions and propose a test involving the scaling relation which may be used to check these values. PACS numbers: 05.50.+q, 05.70.fh, 61.41.+e Short Title: A Scaling Theory of the Collapse Transition ∗email: brak,aleks,[email protected]